何明阳教授
Email: hmyATcczu.edu.cn
教育经历:
1997/09 – 2010/05,南京理工大学,化学化工学院,化学工程专业,博士
1978/05 – 1982/05,江苏化工学院(现新葡萄88805官网),化工系,有机合成专业,学士
工作经历:
2006/07-至今,新葡萄88805官网(原江苏工业学院), 新葡萄88805官网, 教授
1995.7-2006.7, 江苏工业学院(原江苏新葡萄88805官网), 化工系, 副教授
1982/05- 1995/07,江苏新葡萄88805官网(原江苏化工学院), 化工系, 讲师
行政履历:
2010/03-2017/04,新葡萄88805官网,新葡萄88805官网,院长;
1995/07- 1997/08,江苏新葡萄88805官网(现新葡萄88805官网),教务处,处长;
1992/06 -1995/06,江苏化工学院(现新葡萄88805官网),应用化学系,主任;
个人荣誉:
2008年享受国务院特殊津贴;
2006何明阳(排名第二)“苯酚烷基化清洁催化技术及工业应用”项目研究,2006年度国家科技进步二等奖;
2005何明阳(排名第二)“苯酚丙酮缩合催化剂的研制及在万吨级双酚A工业装置上的应用”项目研究,2005年度江苏省科技进步一等奖。
社会兼职:
南京理工大学兼职博士生导师,江苏省精细石油化工重点实验室副主任。
研究方向:
聚合物离子交换催化材料的合成、结构、性能与应用研究;
精细化学品清洁生产工艺与技术;
与清洁环境和能源相关的功能金属-有机框架(MOF)材料的合成、结构与应用研究。
教学科研项目:
2016可见光氧化还原/过渡金属协同催化的C-H官能化研究,国家自然科学基金面上项目,负责反应设计;
2015微纳态有机交联双功能聚合物催化剂的开发企业项目负责人;
2014高产环氧乙烷过程中产品质量瓶颈问题解决措施研究中石化项目主要参与者;
2013骨架镍固定床加氢催化剂的开发中石化项目负责人;
2013聚乙丙交酯医药缓释材料的开发企业项目主要参与者;
2013可降解材料聚乙醇酸的模试研究及工艺包开发中石化项目主要参与者
2013 40万吨/年乙二醇催化加氢装置工艺包开发中石化项目主要参与者;
2013 2-甲氧基乙醇催化水解制乙二醇工艺研究项目主要参与者;
2013双酚A催化剂开发企业项目主要参与者;
2012合成气制乙二醇副产乙醇酸甲酯利用技术开发中石化项目主要参与者;
2012乙二醇产品精制项目企业项目主要参与者;
2011高选择性低流失离子交换树脂催化剂的开发项目主要参与者;
2011 10000T/年乙醛酸生产技术创新企业项目主要参与者;
2010吸氧聚酯包装材料的研究和开发中石化项目主要参与者;
2010加氢法提高乙二醇产品质量的工业化试验中石化项目主要参与者;
2010新型催化剂的开发企业项目主要参与者;
2010双三苯基铬酸酯的开发企业项目主要参与者;
发表论文:
Weiyou Zhou, Qianyun Tao, Fu'an Sun, Xinbai Cao, Junfeng Qian, Jie Xu, Mingyang He*, Qun Chen, and Jianliang Xiao. Additive-free aerobic oxidative dehydrogenation of N-heterocycles under catalysis by NiMn layered hydroxide compounds. J. Catal. 2018,361, 1–11.
Liang Wang, Jun Shen, Sen Yang, Wenjie Liu, Qun Chen and Mingyang He*, C-H arylation reactions through aniline activation catalysed by a PANI-g-C3N4-TiO2 composite under visible light in aqueous medium, Green Chem., 2018, 20, 1290-1296.
Fu'an Sun, Jiacheng Zhou, Weiyou Zhou*, Jiugao Pan, Junfeng Qian, Mingyang He*, Qun Chen. Efficient aerobic oxidation of alcohols catalyzed by NiGa hydrotalcites in the absence of any additives. New J. Chem. 2018,42, 4029–4035.
Liang Wang, Yaoyao Wang, Jun Shen, Qun Chen and Ming-Yang He*, Nickel-catalyzed cyanation of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine, Org. Biomol. Chem., 2018, 16, 4816-4820.
Sheng-Chun Chen, Nan Li, Feng Tian, Nan-Nan Chai, Ming-Yang He* and Qun Chen*, Mild direct amination of benzoxazoles using interpenetrating Cobalt(II)-based metal-organic framework as an efficient heterogeneous catalyst, Molecular Catalysis, 2018, 450, 104-111.
Liang Wang, Sen Yang, Le Chen, Sheng Yuan, Qun Chen, Ming-Yang He* and Zhi-Hui Zhang* Magnetically recyclable Cu-BTC@Fe3O4 composite-catalyzed C(aryl)–S–P bond formation using aniline, P(O)H compounds and sulfur powder Catal. Sci. Technol., 2017, 7, 2356–2361.
Weiyou Zhou, Jiacheng Zhou, Yong Chen, Aijun Cui, Fu'an Sun, Mingyang He, Zhixiang Xu and Qun Chen, Metallophthalocyanine intercalated layered double hydroxides as an efficient catalyst for the selective epoxidation of olefin with oxygen, Appl. Catal. A2017, 542, 191-200.
Zhou, Wei-You, Peng Tian, Fu'an Sun, Ming-Yang He*, and Qun Chen. Highly Efficient Transformation of Alcohol to Carbonyl Compounds under a Hybrid Bifunctional Catalyst Originated from Metalloporphyrins and Hydrotalcite.J. Catal.2016, 335, 105-116.
Sheng-Chun Chen, An-Qi Dai, Kun-Lin Huang, Zhi-Hui Zhang, Ai-Jun Cui, Ming-Yang He*, and Qun Chen*. Assembly of 1d, 2d and 3d Lanthanum(Iii) Coordination Polymers with Perchlorinated Benzenedicarboxylates: Positional Isomeric Effect, Structural Transformation and Ring-Opening Polymerisation of Glycolide. Dalton Trans. 2016, 45(8), 3577-3589.
Weiyou Zhou, Qianyun Tao, Jiugao Pan, Jie Liu, Junfeng Qian, Mingyang He*, and Qun Chen. Effect of Basicity on the Catalytic Properties of Ni-Containing Hydrotalcites in the Aerobic Oxidation of Alcohol. J. Mol. Catal. A-Chem., 2016, 425, 255-265.
Weiyou Zhou, Yong Chen, Junfeng Qian, Fu'an Sun, Mingyang He*, and Qun Chen. Copper Tetrasulfophthalocyanine Intercalated Hydrotalcite as an Efficient Bifunctional Catalyst for the Baeyer-Villiger Oxidation. Catal. Lett, 2016, 146(10), 2157-2164.
Le Chen, Yue-Wei Wang, Ming-Yang He, Qun Chen*, and Zhi-Hui Zhang*. Facile Synthesis of 5a Zeolite from Attapulgite Clay for Adsorption of N-Paraffins. Adsorption, 2016, 22(3), 309-314.
Le Chen, Sheng Yuan, Jun-Feng Qian, Wei Fan, Ming-Yang He, Qun Chen*, and Zhi-Hui Zhang*. Effective Adsorption Separation of N-Hexane/2-Methylpentane in Facilely Synthesized Zeolitic Imidazolate Frameworks Zif-8 and Zif-69. Ind. Eng. Chem. Res., 2016, 55(40), 10751-10757.
Zhi-Hui Zhang, Xu-Sheng Yang, Qing-Qing Zhang, Liang Wang, Ming-Yang He, Qun Chen*, and Xian-Feng Huang*. Structure-Induced Catalysis Enhancement of Cu-Amino Catalysts for Rapidly Selective Oxidation of Sulfides in the Presence of H2o2. Rsc Adv., 2016, 6(106), 104036-104040.
Zhi-Hui Zhang, Xu-Sheng Yang, Wei Guo, Sheng-Chun Chen, Ming-Yang He*, and Qun Chen. Positional Isomeric Effect on Cu-Ii and Cd-Ii Complexes Based on Perfluorinated Dicarboxylate Ligands and Bipyridyl Co-Tectons. Polyhedron, 2016, 117, 695-702.
Liang Wang, Cancan Wang, Wenjie Liu, Qun Chen, and Mingyang He*. Visible-Light-Induced Aerobic Thiocyanation of Indoles Using Reusable Tio2/Mos2 Nanocomposite Photocatalyst. Tetrahedron Lett. , 2016, 57(16), 1771-1774.
Liang Wang, Liang Pan, Yibo Huang, Qun Chen, and Mingyang He*. Palladium-Catalyzed Regioselective C-H Acetoxylation of 2-Aryloxypyridines with 2-Pyridyloxy as a Removable Directing Group. Eur. J. Org. Chem. , 2016, 18, 3113-3118.
Liang Pan, Liang Wang, Qun Chen, and Mingyang He*. Palladium-Catalyzed Oxime Ether Directed Regioselective C-H Alkoxylation of Arenes. Synth. Commun. , 2016, 46(24), 1981-1988.
Liang Wang, Jing Cao, Qun Chen, and Ming-Yang He*. One-Pot Synthesis of 2,5-Diaryl 1,3,4-Oxadiazoles Via Di-Tert-Butyl Peroxide Promoted N-Acylation of Aryl Tetrazoles with Aldehydes. J. Org. Chem., 2015, 80 (9), 4743-4748.
LiangWang, Kai-qiang Zhu, Qun Chen, and Ming-Yang He*. Facile and Environmentally Friendly Halogenation of Bodipys in Deep Eutectic Solvent. Dyes Pigm., 2015, 112, 274-279.
Liang Wang, Kai-qiang Zhu, Wen-ting Wu, Qun Chen, and Ming-Yang He*. N-Bu4ni-Catalyzed Direct Amination of Ethers with Aryl Tetrazoles and Triazoles Via Cross-Dehydrogenative Coupling Reaction. Catal. Sci. Technol., 2015, 5 (5), 2891-2896.
Sheng-Chun Chen, Feng Tian, Kun-Lin Huang,* Cheng-Peng Li, Jing Zhong,Ming-Yang He, Zhi-Hui Zhang, Hong-Ning Wang, Miao Du* and Qun Chen.*Solvent-mediated assembly of chiral/achiral hydrophilic Ca(II)-tetrafluoroterephthalate coordination frameworks: 3D chiral water aggregation, structural transformation and selective CO2 adsorption. CrystEngComm2014, 16, 7673-7680.
Zhi-Hui Zhang,* Qing-Qing Zhang, Sheng Feng,* Zhao-Jian Hu, Sheng-Chun Chen, Qun Chen and Ming-Yang He.* Fluorinated metal-organic frameworks of 1,4-bis(1,2,4-triazol-1-ylmethyl) -2,3,5,6-tetrafluorobenzene: synergistic interactions of ligand isomerism and counteranions. Dalton Trans.2014, 43, 646-655.
Liang Wang,* Kaiqiang Zhu, Qun Chen, and Mingyang He.* Transition-Metal-Free Direct Alkylation of Aryl Tetrazoles via Intermolecular Oxidative C−N Formation. J. Org. Chem.2014, 79, 11780-11786.
Sheng-Chun Chen , Zhi-Hui Zhang, Qun Chen,* Li-Qun Wang , Juan Xu ,Ming-Yang He , Miao Du,* Xiao-Ping Yang and Richard A. Jones* An efficient strategy to achieve hydrophilic polymeric silver(I) materials with exceptional antibacterial activity Chem. Commun. 2013, 1270–1272.
Junfeng Qian, Qiuhui Yang, Fuan Sun, Mingyang He, Qun Chen,* Zhi Yun, Lizhen Qin Cogeneration of biodiesel and nontoxic rapeseed meal from rapeseed through in-situ alkaline transesterification Bioresour. Technol. 2013, 128, 8–13.
Zhi-Hui Zhang, Sheng-Chun Chen, Ming-Yang He, Qun Chen*, and Miao Du* Coordination Assembly of ZnII/CdII Terephthalate with Bis-Pyridinecarboxamide Tectons: Establishing Net Entanglements from [3 + 3] Interpenetration to High-Connected Self-Penetration Cryst. Growth Des.2013, 13, 996–1001.
专著
化工分析技术,2010年,化学工业出版社
授权专利
耐温季铵型阴离子交换树脂相转移催化剂及其制备方法(授权号:ZL200910235073.8)
一种连续化制备高分子量聚羟基酸的方法(授权号:ZL201310168201.8)
具有荧光性能的热稳定性Ni配合物及其制备方法(授权号:ZL201210351486.4)
钴-氨基酸配合物催化剂、制备方法及其应用(授权号:ZL201310052773.X)
一种聚羟基羧酸酯及其制备方法(授权号:ZL201210227364.4)
一种制备脂肪族聚草酸酯的方法(授权号:ZL201210229158.7)
采用凹凸棒土制备直链烷烃吸附用5A分子筛的方法(授权号:ZL201310074773.X)
磺酸基功能化己内酰胺酸性离子液体及其制备方法(授权号:ZL201110003473.3)
一种吸氧剂及含有该吸氧剂的单层瓶吸氧聚酯材料(授权号:ZL201210228773.6)
聚(对苯二甲酸乙二醇酯-CO-乙醇酸酯)共聚酯及其制备方法(授权号:ZL201210227818.8)
水溶性光稳定银(I)配合物、制备方法及其应用 (授权号:ZL201110003487.5)